Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality
نویسندگان
چکیده
منابع مشابه
Recent progress in Lewis acid–Lewis base bifunctional asymmetric catalysis*
Two enantioselective cyanation reactions, the Strecker reaction of ketoimines and the Reissert reaction of pyridine derivatives, promoted by Lewis acid–Lewis base bifunctional asymmetric catalysts are described.
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Sulfoxides are uncommon substrates for transition-metal catalysis due to their propensity to inhibit catalyst turnover. In a collaborative effort with Ken Houk, we developed the first dynamic kinetic resolution (DKR) of allylic sulfoxides using asymmetric rhodium-catalyzed hydrogenation. A detailed mechanistic analysis of this transformation using both experimental and theoretical methods revea...
متن کاملAsymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality† †Electronic supplementary information (ESI) available: Experimental details and analytical data, including chiral HPLC traces and X-ray crystallographic data. CCDC 1027144–1027147, 1028075 and 1014508. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03101f Click here for additional data file. Click here for additional data file.
Fachbereich Chemie, Philipps-Universität Marburg, Germany. E-mail: meggers@chem Department of Chemical Biology and Key L Province, College of Chemistry and Che Xiamen 361005, People's Republic of China † Electronic supplementary information ( analytical data, including chiral HPLC t CCDC 1027144–1027147, 1028075 and 1 data in CIF or other electronic format see ‡ Both authors contributed equally...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c4sc03101f